The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions of tons per year to a few grams per year. The diversity of catalysts is large and encompasses all the known categories of catalyst type: homogeneous, heterogeneous, and biological. This book summarizes the current status in these fields concentrating on rates, kinetics, and reaction mechanisms, but also covers broad topics including modeling, computational simulation, process concepts, spectroscopy and new catalyst development. The similarities and distinctions between the different reaction systems are compared, and the latest advances are described. - Comprehensive listing of epoxide products - Broad comparison of turnover frequencies of homogeneous, hetergeneous, main-group, biomimetic and biological catalysts - Analysis of the general strengths and weaknesses of varied catalytic systems - Detailed description of the mechanisms of reaction for classical and emerging catalysts

The book includes a historical introduction to organometallic chemistry, a survey of mechanisms, and an extensive introduction to quantum mechanical computational methods.

Homogeneous Oxidation Reactions, a volume in the Advances Homogeneous in Catalysis series, covers oxidation and hydrogenation reactions in detail. Split into two sections, the first is devoted to various homogeneous oxidation processes, such as oxidation of olefins, phenols, and aromatic acids. The second presents homogeneous hydrogenation reactions and related processes, including hydrogenation of alkenes, esters, and olefins. Relevant reactor design, industrial case studies, economic analysis and environmental issues of both oxidation and hydrogenation homogeneous reactions are considered. This book will be of particular interest and benefit to catalysts users, manufacturers, and creators. - Includes fundamentals, reactor design and process description of oxidation homogeneous reactions - Describes various oxidation homogeneous reactions - Explains oxidation economic and environmental challenges

This book describes a detailed multi-scale approach integrating nano- (active site), meso- (porous catalyst architecture) and macroscale (reactor) efforts, to address the challenges of producing a better epoxidation catalyst. It contains an in-depth study of the design and synthesis of gold nanoparticles and their application as a catalyst for direct gas phase propylene epoxidation. “Direct” means using only hydrogen and oxygen in one step, which is key for sustainable manufacturing, as opposed to commercialised, more complex production routes requiring multiple steps, or integration with another chemical plant. The insights gained can be used for rational design for stable and selective catalysts for other reactions. It also details the step-by-step process to build an epoxidation reactor system with a focus on safety aspects, which can be used as a guidebook for undergraduate and graduate students in chemical engineering. Beyond heterogeneous catalysis, the new, easily accomplished methodology for synthesising atomically precise nanoparticles is shown to be relevant to electrocatalysis and to healthcare applications, such as anti-microbial surfaces. This book will be of interest to researchers, engineers and experts in the related areas of chemical engineering, chemistry, material science and electrochemistry.

Iron Catalysis: Design and Applications is an exciting new book that takes readers inside the world of iron catalysis guided by international catalysis expert, Dr Jose M Palomo. Iron is the most abundant metal in the planet, cost-effective, environmentally friendly, with an easily manipulated remediation process. In the last few years the use of this nonprecious metal has gained extraordinary attention particularly for its potential as a catalyst in different areas. This book compiles a series of chapters describing the most significant advances in the last few years since the design of different iron catalysts and nanocatalysts and iron-containing artificial and natural enzymes. The chapters also cover its application in different areas of interest such as organic synthesis, environmental remediation, enzyme-like activities or the creation of novel types of electrodes for battery design.

Dieses Handbuch präsentiert die in den letzten zehn Jahren entstandenen neuen Anwendungsbereiche und gibt einen umfassenden Überblick über dieses wissenschaftlich und ökonomisch wichtige Gebiet. Einzigartig ist die Verbindung von Grundlagenforschung und industrieller Entwicklung.

Reflecting the R&D efforts in the field that have resulted in a plethora of novel applications over the past decade, this handbook gives a comprehensive overview of the tangible benefits of nanotechnology in catalysis. By bridging fundamental research and industrial development, it provides a unique perspective on this scientifically and economically important field. While the first three parts are devoted to preparation and characterization of nanocatalysts, the final three provide in-depth insights into their applications in the fine chemicals industry, the energy industry, and for environmental protection, with expert authors reporting on real-life applications that are on the brink of commercialization. Timely reading for catalytic chemists, materials scientists, chemists in industry, and process engineers.

The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.

Magnetic nanocatalysts are becoming an important tool for greener catalytic processes in chemical transformations in view of the ease of their removal from a reaction medium. This book explores assorted magnetic nanocatalysts, their deployment in synthesis, chemical transformation and their recovery and reuse. Various thematic topics embodied include magnetic nanocatalysts for S-S bond formation, N-heterocycle formation, C-heteroatom bond formation, silica-supported catalysts, multicomponent reactions, including their recyclability; another available volume emphasizes the utility of magnetic nanocatalysts in industrial appliances.

Metal Oxide–Based Heterostructures: Fabrication and Applications provides information on synthesis strategies, structural and hierarchical features, morphological characteristics of metal oxide–based heterostructures, and their diverse applications. This book begins with an introduction to the various multidimensional heterostructures, synthesis aspects, and techniques used to control the formation of heterostructures. Then, the impact of synthesis routes on the formation of mixed metal oxide heterostructures and their properties are analyzed. The effect of nonmetal doping, metal doping, and composites of metal oxide heterostructures on the properties of heterostructures is also addressed and that also includes opportunities for optimization of the material's performance for specific applications. Special attention is given to the surface characteristics of the metal oxide heterostructures and their impact on the material's performance, and the applications of metal oxide heterostructures in various fields such as environmental remediation, sensing, organic catalysis, photovoltaics, light emitting materials, and hydrogen production. - Introduces key principles for metal oxide heterostructures, their properties, key characteristics, and synthesis routes - Emphasizes the relationship between synthesis strategies and material performance, including optimization strategies such as tailoring the material's surface characteristics or structure - Discusses metal oxide heterostructures and their application in lighting and displays, energy, environment, and sensing