Volume 8 of Reviews in Mineralogy deals with both descriptions of the kinetics of geochemical processes: the phenomenological and the atomistic. The former relies on macroscopic variables (e.g. temperature or concentrations) to describe the rates of

Volume 8 of Reviews in Mineralogy treats a Short Course in Kinetics, which brings together the fundamentals needed to explain field observations using kinetic data. It is hoped that this book may serve, not only as a reference for researchers dealing with the rates of geochemical processes, but also as a text in courses on geochemical kinetics. The book is organized with a rough temperature gradient in mind, i.e. low temperature kinetics at the beginning and igneous kinetics at the end. However, the topics in each chapter are general enough that they can be applied often to any geochemical domain: sedimentary, metamorphic or igneous. The theory of kinetics operates at two complementary levels: the phenomenological and the atomistic. The former relies on macroscopic variables (e.g. temperature or concentrations) to describe the rates of reactions or the rates of transport; the latter relates the rates to the basic forces operating between the particular atomic or molecular species of any system. This book deals with both descriptions of the kinetics of geochemical processes.

This well-organised, comprehensive reference and textbook describes rate models developed from fundamental kinetic theory and presents models using consistent terminology and notation. Major topics include rate equations, reactor theory, transition state theory, surface reactivity, advective and diffusive transport, aggregation kinetics, nucleation kinetics and solid-solid transformation rates. The theoretical basis and mathematical derivation of each model is presented in detail and illustrated with worked examples from real-world applications to geochemical problems. The book is also supported by online resources: self-study problems put students' new learning into practice, and spreadsheets provide the full data used in figures and examples, enabling students to manipulate the data for themselves. This is an ideal overview for graduate students, providing a solid understanding of geochemical kinetics. It will also provide researchers and professional geochemists with a valuable reference for solving scientific and engineering problems.

Geochemical kinetics as a topic is now of importance to a wide range of geochemists in academia, industry, and government, and all geochemists need a rudimentary knowledge of the field. This book summarizes the fundamentals of geochemical kinetics with examples drawn especially from mineral dissolution and precipitation. It also encompasses discussion of high temperature processes and global geochemical cycle modeling. Analysis of textures of rocks, sediments, and mineral surfaces are incorporated throughout and provide a sub-theme of the book.

This book offers a comprehensive exploration of geochemical kinetics--the application of chemical kinetics to geological problems, both theoretical and practical. Geochemical Kinetics balances the basic theories of chemical kinetics with a thorough examination of advanced theories developed by geochemists, such as nonisothermal kinetics and inverse theories, including geochronology (isotopic dating), thermochronology (temperature-time history), and geospeedometry (cooling rates). The first chapter provides an introduction and overview of the whole field at an elementary level, and the subsequent chapters develop theories and applications for homogeneous reactions, mass and heat transfer, heterogeneous reactions, and inverse problems. Most of the book's examples are from high-temperature geochemistry, with a few from astronomy and environmental sciences. Appendixes, homework problems for each major section, and a lengthy reference list are also provided. Readers should have knowledge of basic differential equations, some linear algebra, and thermodynamics at the level of an undergraduate physical chemistry course. Geochemical Kinetics is a valuable resource for anyone interested in the mathematical treatment of geochemical questions.

This book provides a comprehensive introduction to the field of geochemistry. The book first lays out the ‘geochemical toolbox’: the basic principles and techniques of modern geochemistry, beginning with a review of thermodynamics and kinetics as they apply to the Earth and its environs. These basic concepts are then applied to understanding processes in aqueous systems and the behavior of trace elements in magmatic systems. Subsequent chapters introduce radiogenic and stable isotope geochemistry and illustrate their application to such diverse topics as determining geologic time, ancient climates, and the diets of prehistoric peoples. The focus then broadens to the formation of the solar system, the Earth, and the elements themselves. Then the composition of the Earth itself becomes the topic, examining the composition of the core, the mantle, and the crust and exploring how this structure originated. A final chapter covers organic chemistry, including the origin of fossil fuels and the carbon cycle’s role in controlling Earth’s climate, both in the geologic past and the rapidly changing present. Geochemistry is essential reading for all earth science students, as well as for researchers and applied scientists who require an introduction to the essential theory of geochemistry, and a survey of its applications in the earth and environmental sciences. Additional resources can be found at: www.wiley.com/go/white/geochemistry

This book provides a comprehensive overview of reaction processes in the Earth's crust and on its surface, both in the laboratory and in the field. A clear exposition of the underlying equations and calculation techniques is balanced by a large number of fully worked examples. The book uses The Geochemist's Workbench® modeling software, developed by the author and already installed at over 1000 universities and research facilities worldwide. Since publication of the first edition, the field of reaction modeling has continued to grow and find increasingly broad application. In particular, the description of microbial activity, surface chemistry, and redox chemistry within reaction models has become broader and more rigorous. These areas are covered in detail in this new edition, which was originally published in 2007. This text is written for graduate students and academic researchers in the fields of geochemistry, environmental engineering, contaminant hydrology, geomicrobiology, and numerical modeling.

Volume 70 of Reviews in Mineralogy and Geochemistry represents an extensive review of the material presented by the invited speakers at a short course on Thermodynamics and Kinetics of Water-Rock Interaction held prior to the 19th annual V. M. Goldschmidt Conference in Davos, Switzerland (June 19-21, 2009). Contents: Thermodynamic Databases for Water-Rock Interaction Thermodynamics of Solid Solution-Aqueous Solution Systems Mineral Replacement Reactions Thermodynamic Concepts in Modeling Sorption at the Mineral-Water Interface Surface Complexation Modeling: Mineral Fluid Equilbria at the Molecular Scale The Link Between Mineral Dissolution/Precipitation Kinetics and Solution Chemistry Organics in Water-Rock Interactions Mineral Precipitation Kinetics Towards an Integrated Model of Weathering, Climate, and Biospheric Processes Approaches to Modeling Weathered Regolith Fluid-Rock Interaction: A Reactive Transport Approach Geochemical Modeling of Reaction Paths and Geochemical Reaction Networks

This RiMG (Reviews in Mineralogy & Geochemistry) volume includes contributions that review experimental, characterization, and modeling advances in our understanding of pore-scale geochemical processes. The volume had its origins in a special theme session at the 2015 Goldschmidt Conference in Prague. From a diversity of pore-scale topics that ranged from multi-scale characterization to modeling, this work summarizes the state-of-the-science in this subject. Topics include: modification of thermodynamics and kinetics in small pores. chemo-mechanical processes and how they affect porosity evolution in geological media. small angle neutron scattering (SANS) techniques. how isotopic gradients across fluid–mineral boundaries can develop and how these provide insight into pore-scale processes. Information on an important class of models referred to as "pore network" and much more. The material in this book is accessible for graduate students, researchers, and professionals in the earth, material, environmental, hydrological, and biological sciences. The pore scale is readily recognizable to geochemists, and yet in the past it has not received a great deal of attention as a distinct scale or environment that is associated with its own set of questions and challenges. Is the pore scale merely an environment in which smaller scale (molecular) processes aggregate, or are there emergent phenomena unique to this scale? Is it simply a finer-grained version of the "continuum" scale that is addressed in larger-scale models and interpretations? The scale is important because it accounts for the pore architecture within which such diverse processes as multi-mineral reaction networks, microbial community interaction, and transport play out, giving rise to new geochemical behavior that might not be understood or predicted by considering smaller or larger scales alone.

Written expressly for undergraduate and graduate geologists, this book focuses on how geochemical principles can be used to solve practical problems. The attention to problem-solving reflects the authors'belief that showing how theory is useful in solving real-life problems is vital for learning. The book gives students a thorough grasp of the basic principles of the subject, balancing the traditional equilibrium perspective and the kinetic viewpoint. The first half of the book considers processes in which temperature and pressure are nearly constant. After introductions to the laws of thermodynamics, to fundamental equations for flow and diffusion, and to solution chemistry, these principles are used to investigate diagenesis, weathering, and natural waters. The second half of the book applies thermodynamics and kinetics to systems undergoing changes in temperature and pressure during magmatism and metamorphism. This revised edition incorporates new geochemical discoveries as examples of processes and pathways, with new chapters on mineral structure and bonding and on organic matter and biomarkers. Each chapter has worked problems, and the authors assume that the student has had a year of college-level chemistry and a year of calculus. Praise for the first edition "A truly modern geochemistry book.... Very well written and quite enjoyable to read.... An excellent basic text for graduate level instruction in geochemistry." --Journal of Geological Education "An up-to-date, broadly conceived introduction to geochemistry.... Given the recent flowering of geochemistry as an interdisciplinary science, and given the extent to which it now draws upon the fundamentals of thermodynamics and kinetics to understand earth and planetary processes, this timely and rigorous [book] is welcome indeed." --Geochimica et Cosmochimica Acta