A one-semester undergraduate or graduate-level laboratory course in the basics of electrochemistry, including cyclic voltammetry, pulse techniques, stripping voltammetry, quantitative analysis, EIS, and simulation of data.

Showing how to apply the theoretical knowledge in practice, the one and only compilation of electrochemical experiments on the market now in a new edition. Maintaining its didactic approach, this successful textbook provides clear and easy-to-follow instructions for carrying out the experiments, illustrating the most important principles and applications in modern electrochemistry, while pointing out the potential dangers and risks involved. This second edition contains 84 experiments, many of which cover electrochemical energy conversion and storage as well as electrochemical equilibrium.

Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)

The only comprehensive collection of easy-to-perform electrochemical experiments for both high school lessons and university lab courses. It illustrates the broad area of electrochemistry with respect to thematic aspects and apparatus used in the experiments. In addition, it highlights the interdisciplinary connections to related fields. Following a brief overview, the book goes on to deal with electrochemistry at equilibrium and with flowing current, while further chapters cover analytical electrochemistry, non-traditional methods, electrochemical energy storage and conversion as well as technical electrochemistry. Throughout, the author clearly describes every detail of the experiments and gives helpful guidance for the production of rare working materials. Complementing textbooks on electrochemistry, this is a must for lecturers as well as for students in chemistry.

The Second Edition of Introduction to Electrochemical Science and Engineering outlines the basic principles and techniques used in the development of electrochemical engineering related technologies, such as fuel cells, electrolyzers, and flow-batteries. Covering topics from electrolyte solutions to electrochemical energy conversion systems and corrosion, this revised and expanded edition provides new educational material to help readers familiarize themselves with some of today’s most useful electrochemical concepts. The Second Edition includes a new Appendix C with a detailed description of how the most common electrochemical laboratories can be organized, what data should be collected, and how the data should be treated and presented in a report. Video demonstrations for these laboratories are available on YouTube. In addition, the author has added conceptual and numerical exercises to all of the chapters to help with the understanding of the book material and to extend the important aspects of the electrochemical science and engineering. Finally, electrochemical impedance spectroscopy is now used in most electrochemical laboratories, and so a new section briefly describes this technique in Chapter 7. This new edition Ensures readers have a fundamental knowledge of the core concepts of electrochemical science and engineering, such as electrochemical cells, electrolytic conductivity, electrode potential, and current–potential relations related to a variety of electrochemical systems Develops the initial skills needed to understand an electrochemical experiment and successfully evaluate experimental data without visiting a laboratory Promotes an appreciation of the capabilities and applications of key electrochemical techniques Features eight lab descriptions and instructions that can be used to develop the labs by instructors for a university electrochemical engineering class Integrates eight online videos with lab demonstrations to advise instructors and students on how the labs can be carried out Features a solutions manual for adopting instructors The Second Edition is an ideal and unique text for undergraduate engineering and science students and readers in need of introductory-level content. Graduate students and engineers looking for a quick introduction to the subject will benefit from the simple structure of this book. Instructors interested in teaching the subject to undergraduate students can immediately use this book without reservation.

This book covers the fundamental aspects and the application of electrochemical impedance spectroscopy (EIS), with emphasis on a step-by-step procedure for mechanistic analysis of data. It enables the reader to learn the EIS technique, correctly acquire data from a system of interest, and effectively interpret the same. Detailed illustrations of how to validate the impedance spectra, use equivalent circuit analysis, and identify the reaction mechanism from the impedance spectra are given, supported by derivations and examples. MATLAB® programs for generating EIS data under various conditions are provided along with free online video lectures to enable easier learning. Features: Covers experimental details and nuances, data validation method, and two types of analysis – using circuit analogy and mechanistic analysis Details observations such as inductive loops and negative resistances Includes a dedicated chapter on an emerging technique (Nonlinear EIS), including code in the supplementary material illustrating simulations Discusses diffusion, constant phase element, porous electrodes, and films Contains exercise problems, MATLAB codes, PPT slide, and illustrative examples This book is aimed at senior undergraduates and advanced graduates in chemical engineering, analytical chemistry, electrochemistry, and spectroscopy.

Das führende Werk auf seinem Gebiet - jetzt durchgängig auf den neuesten Stand gebracht! Die theoretischen Grundlagen der Elektrochemie, erweitert um die aktuellsten Erkenntnisse in der Theorie des Elektronentransfers, werden hier ebenso besprochen wie alle wichtigen Anwendungen, darunter modernste Verfahren (Ultramikroelektroden, modifizierte Elektroden, LCEC, Impedanzspektrometrie, neue Varianten der Pulsvoltammetrie und andere). In erster Linie als Lehrbuch gedacht, läßt sich das Werk aber auch hervorragend zum Selbststudium und zur Auffrischung des Wissensstandes verwenden. Lediglich elementare Grundkenntnisse der physikalischen Chemie werden vorausgesetzt.

Using electrochemical impedance spectroscopy in a broad range of applications This book provides the background and training suitable for application of impedance spectroscopy to varied applications, such as corrosion, biomedical devices, semiconductors and solid-state devices, sensors, batteries, fuel cells, electrochemical capacitors, dielectric measurements, coatings, electrochromic materials, analytical chemistry, and imaging. The emphasis is on generally applicable fundamentals rather than on detailed treatment of applications. With numerous illustrative examples showing how these principles are applied to common impedance problems, Electrochemical Impedance Spectroscopy is ideal either for course study or for independent self-study, covering: Essential background, including complex variables, differential equations, statistics, electrical circuits, electrochemistry, and instrumentation Experimental techniques, including methods used to measure impedance and other transfer functions Process models, demonstrating how deterministic models of impedance response can be developed from physical and kinetic descriptions Interpretation strategies, describing methods of interpretating of impedance data, ranging from graphical methods to complex nonlinear regression Error structure, providing a conceptual understanding of stochastic, bias, and fitting errors in frequency-domain measurements An overview that provides a philosophy for electrochemical impedance spectroscopy that integrates experimental observation, model development, and error analysis This is an excellent textbook for graduate students in electrochemistry, materials science, and chemical engineering. It's also a great self-study guide and reference for scientists and engineers who work with electrochemistry, corrosion, and electrochemical technology, including those in the biomedical field, and for users and vendors of impedance-measuring instrumentation.

This text probes topics and reviews progress in interfacial electrochemistry. It supplies chapter abstracts to give readers a concise overview of individual subjects and there are more than 1500 drawings, photographs, micrographs, tables and equations. The 118 contributors are international scholars who present theory, experimentation and applications.

This laboratory book delivers hands-on advice to researchers in all fields of life and physical sciences already applying or intending to apply electro-analytical methods in their research. The authors represent in a strictly practice-oriented manner not only the necessary theoretical background but also substantial know-how on measurement techniques, interpretation of data, experimental setup and trouble shooting. The author and the editor are well-known specialists in their field.