High Temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications provides a comprehensive discussion of solid oxide fuel cells (SOFCs). SOFCs are the most efficient devices for the electrochemical conversion of chemical energy of hydrocarbon fuels into electricity, and have been gaining increasing attention for clean and efficient distributed power generation. The book explains the operating principle, cell component materials, cell and stack designs and fabrication processes, cell and stack performance, and applications of SOFCs. Individual chapters are written by internationally renowned authors in their respective fields, and the text is supplemented by a large number of references for further information. The book is primarily intended for use by researchers, engineers, and other technical people working in the field of SOFCs. Even though the technology is advancing at a very rapid pace, the information contained in most of the chapters is fundamental enough for the book to be useful even as a text for SOFC technology at the graduate level.

High-temperature Solid Oxide Fuel Cells, Second Edition, explores the growing interest in fuel cells as a sustainable source of energy. The text brings the topic of green energy front and center, illustrating the need for new books that provide comprehensive and practical information on specific types of fuel cells and their applications. This landmark volume on solid oxide fuel cells contains contributions from experts of international repute, and provides a single source of the latest knowledge on this topic. - A single source for all the latest information on solid oxide fuel cells and their applications - Illustrates the need for new, more comprehensive books and study on the topic - Explores the growing interest in fuel cells as viable, sustainable sources of energy

Intermediate Temperature Solid Oxide Fuel Cells: Electrolytes, Electrodes and Interconnects introduces the fundamental principles of intermediate solid oxide fuel cells technology. It provides the reader with a broad understanding and practical knowledge of the electrodes, pyrochlore/perovskite/oxide electrolytes and interconnects which form the backbone of the Solid Oxide Fuel Cell (SOFC) unit. Opening with an introduction to the thermodynamics, physiochemical and electrochemical behavior of Solid Oxide Fuel Cells (SOFC), the book also discusses specific materials, including low temperature brownmillerites and aurivillius electrolytes, as well as pyrochlore interconnects. This book analyzes the basic concepts, providing cutting-edge information for both researchers and students. It is a complete reference for Intermediate Solid Oxide Fuel Cells technology that will be a vital resource for those working in materials science, fuel cells and solid state chemistry. - Provides a single source of information on glass, electrolytes, interconnects, vanadates, pyrochlores and perovskite SOFC - Includes illustrations that provide a clear visual explanation of concepts being discussed - Progresses from a discussion of basic concepts that will enable readers to easily comprehend the subject matter

Introduction -- History of SOFCs -- Thermodynamics -- Electrolyte -- Cathode -- Anode -- Interconnect (ceramic, metallic) -- Electrode Polarizations -- Fuels and Fuel Processing -- Cell and Stack Designs -- Cell and Stack Modelling -- Cell and Stack Testing -- Applications and Demonstrations.

This book fills the need for a practical reference for all scientists and graduate students who are seeking to define a mathematical model for Solid Oxide Fuel Cell (SOFC) simulation. Structured in two parts, part one presents the basic theory, and the general equations describing SOFC operation phenomena. Part two deals with the application of the theory to practical examples, where different SOFC geometries, configurations, and different phenomena are analyzed in detail.

This volume contains an archival record of the NATO Advanced Institute on Mini – Micro Fuel Cells – Fundamental and Applications held in Çesme – Izmir, Turkey, July 22–August 3, 2007. The ASIs are intended to be a high-level teaching activity in scientific and technical areas of current concern. In this volume, the reader may find interesting chapters on Mini- Micro Fuel Cells with fundamentals and applications. In recent years, fu- cell development, modeling and performance analysis has received much attention due to their potential for distributed power which is a critical issue for energy security and the environmental protection. Small fuel cells for portable applications are important for the security. The portable devices (many electronic and wireless) operated by fuel cells for providing all-day power, are very valuable for the security, for defense and in the war against terrorism. Many companies in NATO and non-NATO countries have concentrated to promote the fuel cell industry. Many universities with industrial partners committed to the idea of working together to develop fuel cells. As tech- logy advanced in the 1980s and beyond, many government organizations joined in spending money on fuel-cell research. In recent years, interest in using fuel cells to power portable electronic devices and other small equipment (cell phones, mobile phones, lab-tops, they are used as micro power source in biological applications) has increased partly due to the promise of fuel cells having higher energy density.

The First Book Centered on Materials Issues of SOFCsAlthough the high operating temperature of solid oxide fuel cells (SOFCs) creates opportunities for using a variety of fuels, including low-grade hydrogen and those derived from biomass, it also produces difficulties in materials performance and often leads to materials degradation during operatio

High temperature solid oxide fuel cell (SOFC) technology is a promising power generation option that features high electrical efficiency and low emissions of environmentally polluting gases such as CO2, NOox and SOx. It is ideal for distributed stationary power generation applications where both high-efficiency electricity and high-quality heat are in strong demand. For the past few decades, SOFC technology has attracted intense worldwide R&D effort and, along with polymer electrolyte membrane fuel cell (PEMFC) technology, has undergone extensive commercialization development.This book presents a systematic and in-depth narrative of the technology from the perspective of fundamentals, providing comprehensive theoretical analysis and innovative characterization techniques for SOFC technology. The book initially deals with the basics and development of SOFC technology from cell materials to fundamental thermodynamics, electronic properties of solids and charged particle transport. This coverage is extended with a thorough analysis of such operational features as current flow and energy balance, and on to voltage losses and electrical efficiency. Furthermore, the book also covers the important issues of fuel cell stability and durability with chapters on performance characterization, fuel processing, and electrode poisoning. Finally, the book provides a comprehensive review for SOFC materials and fabrication techniques. A series of useful scientific appendices rounds off the book.Solid oxide fuel cell technology is a standard reference for all those researching this important field as well as those working in the power industry. - Provides a comprehensive review of solid oxide fuel cells from history and design to chemistry and materials development - Presents analysis of operational features including current flow, energy balance, voltage losses and electrical efficiency - Explores fuel cell stability and durability with specific chapters examining performance characterization, fuel processing and electrode poisoning

In this book well-known experts highlight cutting-edge research priorities and discuss the state of the art in the field of solid oxide fuel cells giving an update on specific subjects such as protonic conductors, interconnects, electrocatalytic and catalytic processes and modelling approaches.Fundamentals and advances in this field are illustrated to help young researchers address issues in the characterization of materials and in the analysis of processes, not often tackled in scholarly books.

Fuel cell technology is quite promising for conversion of chemical energy of hydrocarbon fuels into electricity without forming air pollutants. There are several types of fuel cells: polymer electrolyte fuel cell (PEFC), phosphoric acid fuel cell (PAFC), molten carbonate fuel cell (MCFC), solid oxide fuel cell (SOFC), and alkaline fuel cell (AFC). Among these, SOFCs are the most efficient and have various advantages such as flexibility in fuel, high reliability, simple balance of plant (BOP), and a long history. Therefore, SOFC technology is attracting much attention as a power plant and is now close to marketing as a combined heat and power generation system. From the beginning of SOFC development, many perovskite oxides have been used for SOFC components; for example, LaMnO -based oxide for the cathode and 3 LaCrO for the interconnect are the most well known materials for SOFCs. The 3 current SOFCs operate at temperatures higher than 1073 K. However, lowering the operating temperature of SOFCs is an important goal for further SOFC development. Reliability, durability, and stability of the SOFCs could be greatly improved by decreasing their operating temperature. In addition, a lower operating temperature is also beneficial for shortening the startup time and decreasing energy loss from heat radiation. For this purpose, faster oxide ion conductors are required to replace the conventional Y O -stabilized ZrO 2 3 2 electrolyte. A new class of electrolytes such as LaGaO is considered to be 3 highly useful for intermediate-temperature SOFCs.