Geochemistry of Earth Surface Systems offers an interdisciplinary reference for scientists, researchers and upper undergraduate and graduate level geochemistry students a sampling of articles on earth surface processes from The Treatise on Geochemistry that is more affordable than the full Treatise. For professionals, this volume will provide an overview of the field as a whole. For students, it will provide more in-depth introductory content than is found in broad-based geochemistry textbooks. Articles were selected from chapters across all volumes of the full Treatise, and include: Volcanic Degassing, Hydrothermal Processes, The Contemporary Carbon Cycle, Global Occurrence of Major Elements in Rivers, Organic Matter in the Contemporary Ocean, The Biological Pump, and Evolution of Sedimentary Rocks. Comprehensive, interdisciplinary and authoritative content selected by leading subject experts Robust illustrations, figures and tables Affordably priced sampling of content from the full Treatise on Geochemistry

Geochemistry at the surface of the earth is dominated by two somewhat antagonistic forces: chemical reactions which attempt to attain a steady state (equilibrium) and geological movement of materials in time and space which changes the parameters that control chemical equilibrium. Another aspect that is extremely important to earth surface geochemistry is the effect of plants on the chemical and physical stability of materials (soils). Plant systems in fact work against the normal chemical changes (loss of silica, potassium, etc.) and the normal physical changes (stabilizing fine grained materials (clays) in the surface zones to avoid erosion). Biological effects are clearly seen in redox effects in the various parts of the earth surface movement cycle; soil formation, stream transport, sedimentation. This book attempts to outline these different parameters and their interactions as they affect earth surface geochemistry in order to give a better understanding of movement and accumulation of elements at the surface of the earth.

Topics covered: Geochemical record of terrestrial environmental change, and global geochemical cycles; Chemical weathering and climate, river catchment studies; Environmental geochemistry of the terrestrial environment and its effect on health; Organic geochemistry; Marine and sedimentary geochemistry; Mineralogy, microbes and chemistry of weathering; Geochemical thermodynamics and kinetics; Geochemistry of crustal fluids and of catastrophic events.

During geologic spans of time, Earth's shifting tectonic plates, atmosphere, freezing water, thawing ice, flowing rivers, and evolving life have shaped Earth's surface features. The resulting hills, mountains, valleys, and plains shelter ecosystems that interact with all life and provide a record of Earth surface processes that extend back through Earth's history. Despite rapidly growing scientific knowledge of Earth surface interactions, and the increasing availability of new monitoring technologies, there is still little understanding of how these processes generate and degrade landscapes. Landscapes on the Edge identifies nine grand challenges in this emerging field of study and proposes four high-priority research initiatives. The book poses questions about how our planet's past can tell us about its future, how landscapes record climate and tectonics, and how Earth surface science can contribute to developing a sustainable living surface for future generations.

This book is a brief summary of the course of lectures in Geochemistry for undergraduate and graduate students from other than Geological Departments (chemists, biologists, ecologists and naturalists). It describes the Earth’s structure and some geological processes. The modern geochemical concepts take proper account of global geological processes and the influence of Cosmos. They are based on the laws and approaches of equilibrium and non-equilibrium thermodynamics. The cycles of energy and chemical elements within the Earth are interrelated with the global geochemical cycle. In addition to the traditional Geochemistry course, this book offers Geochemistry of microorganisms, Geochemistry of dispersed systems, Geochemistry of cryogenesis, and Geochemistry of cryptobiosphere. Features: Provides the reader with a general idea of the Earth’s chemical life and its related global geological events Offers a concise and clear description of the modern concepts in Geochemistry, including new directions such as Geochemistry of Cryogenesis, Geochemistry of Disperse Systems, Geochemistry of Microorganisms, and Geochemistry of Cryptobiosphere Implies a wide application of the thermodynamic approach. Useful for students who, though lacking in geology basics, are experienced in chemistry and biology

This book provides a comprehensive introduction to the field of geochemistry. The book first lays out the ‘geochemical toolbox’: the basic principles and techniques of modern geochemistry, beginning with a review of thermodynamics and kinetics as they apply to the Earth and its environs. These basic concepts are then applied to understanding processes in aqueous systems and the behavior of trace elements in magmatic systems. Subsequent chapters introduce radiogenic and stable isotope geochemistry and illustrate their application to such diverse topics as determining geologic time, ancient climates, and the diets of prehistoric peoples. The focus then broadens to the formation of the solar system, the Earth, and the elements themselves. Then the composition of the Earth itself becomes the topic, examining the composition of the core, the mantle, and the crust and exploring how this structure originated. A final chapter covers organic chemistry, including the origin of fossil fuels and the carbon cycle’s role in controlling Earth’s climate, both in the geologic past and the rapidly changing present. Geochemistry is essential reading for all earth science students, as well as for researchers and applied scientists who require an introduction to the essential theory of geochemistry, and a survey of its applications in the earth and environmental sciences. Additional resources can be found at: www.wiley.com/go/white/geochemistry

Colloid science has been applied by soil chemists and clay mineral ogists for many years, and some of the most important studies on the behavior of colloids have been contributed by them. Barring a few notable exceptions, only in the last decade have geochemists applied colloid science in their research and in this period much work has been published. It seemed to the authors that it would be useful at this stage to attempt to summarize the progress made and to try to examine what colloid science has contributed and can further contribute to geo chemistry. This book is based partly on a course of the same title given to graduate students by one of the authors (S. Y) between 1972 and 1977 at the Department of Geology at the Hebrew University of Jerusalem. Consequently many fundamental concepts of the subject are included that will be of use to graduate students in geology, geo chemistry, soil science, and oceanography. So that specialists interested in certain sections may find their subjects comprehensively covered, a few topics are dealt with in more than one chapter so that readers may ignore sections not especially of interest to them. However the chapters more fully treating certain topics are cross-referenced. In such cases the subjects are treated from different viewpoints and the citations used represent these dif fering viewpoints.

The Encyclopedia is a complete and authoritative reference work for this rapidly evolving field. Over 200 international scientists, each experts in their specialties, have written over 330 separate topics on different aspects of geochemistry including geochemical thermodynamics and kinetics, isotope and organic geochemistry, meteorites and cosmochemistry, the carbon cycle and climate, trace elements, geochemistry of high and low temperature processes, and ore deposition, to name just a few. The geochemical behavior of the elements is described as is the state of the art in analytical geochemistry. Each topic incorporates cross-referencing to related articles, and also has its own reference list to lead the reader to the essential articles within the published literature. The entries are arranged alphabetically, for easy access, and the subject and citation indices are comprehensive and extensive. Geochemistry applies chemical techniques and approaches to understanding the Earth and how it works. It touches upon almost every aspect of earth science, ranging from applied topics such as the search for energy and mineral resources, environmental pollution, and climate change to more basic questions such as the Earth’s origin and composition, the origin and evolution of life, rock weathering and metamorphism, and the pattern of ocean and mantle circulation. Geochemistry allows us to assign absolute ages to events in Earth’s history, to trace the flow of ocean water both now and in the past, trace sediments into subduction zones and arc volcanoes, and trace petroleum to its source rock and ultimately the environment in which it formed. The earliest of evidence of life is chemical and isotopic traces, not fossils, preserved in rocks. Geochemistry has allowed us to unravel the history of the ice ages and thereby deduce their cause. Geochemistry allows us to determine the swings in Earth’s surface temperatures during the ice ages, determine the temperatures and pressures at which rocks have been metamorphosed, and the rates at which ancient magma chambers cooled and crystallized. The field has grown rapidly more sophisticated, in both analytical techniques that can determine elemental concentrations or isotope ratios with exquisite precision and in computational modeling on scales ranging from atomic to planetary.

This book covers the more basic aspects of carbonate minerals and their interaction with aqueous solutions; modern marine carbonate formation and sediments; carbonate diagenesis (early marine, meteoric and burial); the global cycle of carbon and human intervention; and the role of sedimentary carbonates as indicators of stability and changes in the Earth's surface environment. The selected subjects are presented with sufficient background information to enable the non-specialist to understand the basic chemistry involved. Tested on classes taught by the authors, and approved by the students, this comprehensive volume will prove itself to be a valuable reference source to students, researchers and professionals in the fields of oceanography, geochemistry, petrology, environmental science and petroleum geology.

To understand hydrochemistry and to analyze natural as well as man-made impacts on aquatic systems, hydrogeochemical models have been used since the 1960’s and more frequently in recent times. Numerical groundwater flow, transport, and geochemical models are important tools besides classical deterministic and analytical approaches. Solving complex linear or non-linear systems of equations, commonly with hundreds of unknown parameters, is a routine task for a PC. Modeling hydrogeochemical processes requires a detailed and accurate water analysis, as well as thermodynamic and kinetic data as input. Thermodynamic data, such as complex formation constants and solubility-products, are often provided as databases within the respective programs. However, the description of surface-controlled reactions (sorption, cation exchange, surface complexation) and kinetically controlled reactions requires additional input data. Unlike groundwater flow and transport models, thermodynamic models, in principal, do not need any calibration. However, considering surface-controlled or kinetically controlled reaction models might be subject to calibration. Typical problems for the application of geochemical models are: • speciation • determination of saturation indices • adjustment of equilibria/disequilibria for minerals or gases • mixing of different waters • modeling the effects of temperature • stoichiometric reactions (e.g. titration) • reactions with solids, fluids, and gaseous phases (in open and closed systems) • sorption (cation exchange, surface complexation) • inverse modeling • kinetically controlled reactions • reactive transport Hydrogeochemical models depend on the quality of the chemical analysis, the boundary conditions presumed by the program, theoretical concepts (e.g.