Fluid flow, as it applies to geologic media, is the topic of this volume. The range of interest is large; it encompasses the weathering of geologic formations by the action of water, the manner in which certain minerals come to occur in commercial quantities, the fate of chemical contaminants once they enter an aquifer, optimal methods to remove (or at least contain) these contaminants, and ways to improve the recovery of hydrocarbons from reservoirs. While it is impossible to treat all of the applications of geochemical flow in a single volume, it is possible to treat certain features of simplified reactive flow that occur in nearly all applications. Understanding these features will help interpret much more complex flows and providing the basis for this understanding is the goal of this text. This book is a culmination of a research project conducted at The University of Texas at Austin (UT) over the past 20 years. It has also been used as a text in a graduate course at UT on geochemistry and flow, taught by each of the editors over a period of 10 years. The reader will undoubtedly benefit from the knowledge flow that this progression from research project, via classroom, to text represents.

Describes fluid flow, transport and contamination in rocks and sediments, for graduate students and professionals in hydrology, water resources, geochemistry.

Water is one of the world's threatened resources: it is also a substance of importance in Geology. For some years I have felt the need for a book that sets out the fundamentals of fluid mechanics, written for geologists rather than engineers. The efforts to repair my own deficiencies in this respect led me along various unfamiliar paths, few of which were unrewarding. This book is the result of my journeys through the literature and as a geologist in several parts of the world. It has been written for students of geology of all ages, in the simplest terms possible, and it has one objective: to provide a basis for an understanding of the mechanical role of water in geology. It has not been written for experts in ground water hydrology, or specialists in the fluid aspects of structural geology: it has been written for geologists like me who are not very good mathematicians, so that we can take water better into account in our normal geological work, whatever it might be. The fundamentals apply equally to mineralization, geochemistry, and vulcanology although they have not been specifically mentioned. It has also been written for the university student of geology so that he or she may start a career with some appreciation of the importance of water, and understanding of its movement.

1. General Significance of Geochemical Models of Hydrothermal Systems,- 2. Concepts, Classification and Chemistry of Geothermal Systems,- 3.Theory of Chemical Modeling,- 4. Specific Features of Coupled Fluid Flow and Chemical Reaction,- 5. Fossil Hydrothermal Systems,- 6. Recent Hydrothermal Systems,- 7. Reservoir Management.

Seabed fluid flow involves the flow of gases and liquids through the seabed. Such fluids have been found to leak through the seabed into the marine environment in seas and oceans around the world - from the coasts to deep ocean trenches. This geological phenomenon has widespread implications for the sub-seabed, seabed, and marine environments. Seabed fluid flow affects seabed morphology, mineralization, and benthic ecology. Natural fluid emissions also have a significant impact on the composition of the oceans and atmosphere; and gas hydrates and hydrothermal minerals are potential future resources. This book describes seabed fluid flow features and processes, and demonstrates their importance to human activities and natural environments. It is targeted at research scientists and professionals with interests in the marine environment. Colour versions of many of the illustrations, and additional material - most notably feature location maps - can be found at www.cambridge.org/9780521819503.

The formation of ore deposits and the patterns of mineral alteration in rocks frequently involves the transport of large amounts of dissolved solids, sometimes transiently, but often over long periods of time. Knowing or suspecting this, we logically seek to resolve several questions: What are the large- and small-scale patterns of flow in geological materials? What is the direction and rate of flow in a given structure? What factors control the rates of chemical reaction within the rocks? What governs the dissolution of materials in some regions and their deposition in other areas that, over eons, leads to the distribution of minerals we see today? The search for answers to these issues involves a combination of approaches and subjects that includes geochemistry, structural geology, and fluid mechanics. In Flow and Reactions in Permeable Rocks, Dr. Owen Phillips provides the first book-length work that connects these different fields of study and applies them to the problem of flow and flow-controlled reaction in rocks. The author begins by specifying the general physical and chemical principles that govern fluid flow and chemical reactions in rocks. He then develops the theoretical underpinnings for a variety of different patterns of flow and for the three basic types of flow-controlled reaction: fronts, gradient reactions, and reactions in mixing zones. In the next chapter he explores some conditions for stability and instability in fluid flow, for instance the conditions under which one state of flow pattern spontaneously evolves into another. Finally, Dr. Phillips describes in detail the two great driving forces of large-scale fluid circulation in rocks: pressure differences and thermal convection. Typical geological examples are given and, wherever possible, compared to numerical results or field observations. The analytical developments require some familiarity with college-level mathematics, but derivations are easy to follow or may even be skipped by the trusting reader.

The fifth volume in this series is focused on the chemical and physical interactions between rocks undergoing metamorphism and the fluids that they generate and that pass through them. The recognition that such pro cesses can profoundly affect the course of metamorphism has resulted in a number of recent papers and we consider that it is time for a review by some of the interested parties. We hope our selection of contributors provides an adequate cross section and demonstrates some of the flavor of this rapidly developing field. A cursory examination of the volume will reveal that there are widely divergent opinions on the compositions of metamorphic fluids and on the ways in which they interact physically and chemically with the rocks through which they pass. Since our own views are extensively discussed in Chapters 4 and 8, we leave the reader to determine his own brand of the "truth. " We wish to thank D. Bird, S. Bohlen, D. Carmichael, G. Flowers, C. Foster, C. Graham, E. Perry, J. Selverstone, R. Tracy, J. Valley, and R. Wollast for their chapter reviews. Thanks are also due C. Cheverton for her editorial assistance, and the helpful staff at Springer-Verlag New York.

In this updated and expanded second edition, new literature has been added on contaminant fate in the soil-subsurface environment. In particular, more data on the behavior of inorganic contaminants and on engineered nanomaterials were included, the latter comprising a group of “emerging contaminants” that may reach the soil and subsurface zones. New chapters are devoted to a new perspective of contaminant geochemistry, namely irreversible changes in pristine land and subsurface systems following chemical contamination. Two chapters were added on this topic, focusing attention on the impact of chemical contaminants on the matrix and properties of both liquid and solid phases of soil and subsurface domains. Contaminant impacts on irreversible changes occurring in groundwater are discussed and their irreversible changes on the porous medium solid phase are surveyed. In contrast to the geological time scale controlling natural changes of porous media liquid and solid phases, the time scale associated with chemical pollutant induced changes is far shorter and extends over a “human lifetime scale”.

This extensively updated new edition of the widely acclaimed Treatise on Geochemistry has increased its coverage beyond the wide range of geochemical subject areas in the first edition, with five new volumes which include: the history of the atmosphere, geochemistry of mineral deposits, archaeology and anthropology, organic geochemistry and analytical geochemistry. In addition, the original Volume 1 on "Meteorites, Comets, and Planets" was expanded into two separate volumes dealing with meteorites and planets, respectively. These additions increased the number of volumes in the Treatise from 9 to 15 with the index/appendices volume remaining as the last volume (Volume 16). Each of the original volumes was scrutinized by the appropriate volume editors, with respect to necessary revisions as well as additions and deletions. As a result, 27% were republished without major changes, 66% were revised and 126 new chapters were added. In a many-faceted field such as Geochemistry, explaining and understanding how one sub-field relates to another is key. Instructors will find the complete overviews with extensive cross-referencing useful additions to their course packs and students will benefit from the contextual organization of the subject matter Six new volumes added and 66% updated from 1st edition. The Editors of this work have taken every measure to include the many suggestions received from readers and ensure comprehensiveness of coverage and added value in this 2nd edition The esteemed Board of Volume Editors and Editors-in-Chief worked cohesively to ensure a uniform and consistent approach to the content, which is an amazing accomplishment for a 15-volume work (16 volumes including index volume)!