Synthetic fibres are widely used for many applications, with their colour being of major commercial importance. This extensively referenced book provides a comprehensive account of the physical chemistry of the dyeing of synthetic fibres and microfibres.

The production of textile materials comprises a very large and complex global industry that utilises a diverse range of fibre types and creates a variety of textile products. As the great majority of such products are coloured, predominantly using aqueous dyeing processes, the coloration of textiles is a large-scale global business in which complex procedures are used to apply different types of dye to the various types of textile material. The development of such dyeing processes is the result of substantial research activity, undertaken over many decades, into the physico-chemical aspects of dye adsorption and the establishment of ‘dyeing theory’, which seeks to describe the mechanism by which dyes interact with textile fibres. Physico-Chemical Aspects of Textile Coloration provides a comprehensive treatment of the physical chemistry involved in the dyeing of the major types of natural, man-made and synthetic fibres with the principal types of dye. The book covers: fundamental aspects of the physical and chemical structure of both fibres and dyes, together with the structure and properties of water, in relation to dyeing; dyeing as an area of study as well as the terminology employed in dyeing technology and science; contemporary views of intermolecular forces and the nature of the interactions that can occur between dyes and fibres at a molecular level; fundamental principles involved in dyeing theory, as represented by the thermodynamics and kinetics of dye sorption; detailed accounts of the mechanism of dyeing that applies to cotton (and other cellulosic fibres), polyester, polyamide, wool, polyacrylonitrile and silk fibres; non-aqueous dyeing, as represented by the use of air, organic solvents and supercritical CO2 fluid as alternatives to water as application medium. The up-to-date text is supported by a large number of tables, figures and illustrations as well as footnotes and widespread use of references to published work. The book is essential reading for students, teachers, researchers and professionals involved in textile coloration.

Chromic phenomena, or those produced by materials which exhibit colour in response to a chemical or physical stimulus, have increasingly been at the heart of 'high-tec' developments in a variety of fields in the last decade. Many of the newer technologies, which are at the cutting edge of research, are multi-disciplinary, involving researchers from areas as diverse as physics, biology, materials science and electronic engineering. Chromic Phenomena covers five main areas: Colour change materials, such as photochromic, thermochromic and electrochromic materials; Materials which absorb and reflect light - the classical dyes and pigments; Luminescent phenomena, including phosphorescence, fluorescence and electroluminescence; Materials which absorb light and transfer energy, eg photosensitisers, infra-red absorbers and laser-addressable compounds; Phenomena involving the manipulation of light by chemicals, such as liquid crystals, lustre pigments, optoelectronics and photonics Providing an entry point both for new researchers and for established ones, this book, with its emphasis on the technological applications of these chromic phenomena, develops and investigates new applications for colour chemistry. It will be of interest to industrialists and professionals in the biological, medicinal, electronics/telecommunications and colorant industries, as well as academics in these fields.

This volume examines the chemistry of natural and synthetic dyes produced for non-textile markets, where much new basic research in color chemistry is now taking place.The first group of chapters covers the design, synthesis, properties and application technology pertaining to dyes for digital printing and photography. The reader will be pleased with the breadth and depth of information presented in each case. Of particular interest is the discussion of strategies for the design of dyes in these categories, with emphasis on enhancing technical properties. In view of certain new developments, the ink-jet chapter includes results from studies pertaining to dyes for textiles.The three chapters comprising Section II of this volume cover the broad subject of dyes for food, drug and cosmetic applications and then provide an in-depth look at dyes for biomedical applications and molecular recognition. The chapter on dyes for molecular recognition places emphasis on applications in the biological sciences, including sensory materials and artificial receptors. While the former two topics have been covered elsewhere in the past, the present chapters are unequalled in scope.Section III provides an in-depth review of the design of laser dyes and dye-based functional materials. In the first of the two chapters, the major principles of laser operation are summarized. This is followed by a discussion of spectroscopic properties, such as activation and deactivation of absorbed light by laser dyes. Approaches to the development of new laser dyes are presented. The second chapter pertains to the synthesis of dicyanopyrazine-based multifunctional dyes. The visible and fluorescence spectra of these dyes in solution and the solid state are correlated with their three-dimensional molecular structures. Molecular stacking behavior and solid state properties of these "multifunctional" dye materials are presented.The final group of chapters pertains to natural dyes and dyes for natural substrates. In recent years, the impression among certain consumers that "natural" is better/safer has generated much interest in the use of natural dyes rather than synthetics. This has led to a few short discussion papers in which the environmental advantages to using natural dyes have been questioned. The initial chapter in this group provides both a historical look at natural dyes and a comprehensive compilation of natural dye structures and their sources. Though natural dyes are of interest as colorants for textiles, selected ones are used primarily in food and cosmetics.Chapter ten provides an update on the author's previous reviews of structure-color-relationships among precursors employed in the coloration of hair. Chemical constitutions characterizing hair dye structures are presented, along with a summary of available precursors and their environmental properties. Similarly, the chapter on leather dyes covers constitutions and nomenclature, in addition to providing interesting perspectives on the origin and use of leather, the dyeing of leather, and key environmental issues.This volume is concluded with another look at colors in nature. In this case, rather than revisiting colors in plant life, an interesting chapter dealing with color in the absence of colorants is presented. Chapter twelve covers basic concepts of color science and illustrates how 3-D assemblies leading to a plethora of colors are handled in nature. It is our hope that this atypical "color chemistry" chapter will invoke ideas that lead to the design of useful colorants.The chapters presented in this volume demonstrate that color chemistry still has much to offer individuals with inquiring minds who are searching for a career path. This work highlights the creativity of today's color chemists and the wide variety of interesting non-textile areas from which a career can be launched.

With increased environmental awareness and rising costs, manufacturers are investing in real time monitoring and control of dyeing to increase its efficiency and quality. This book reviews ways of automating the dyeing process as well as ways of understanding key processes in dyeing, including dye transport in fluid systems. This understanding is then used to create models to simulate the dyeing process which can then be used to develop appropriate measurement and control systems. Control of variables such as temperature, pH, conductivity and dye concentration can then be used to ensure a more consistent and cost-effective dyeing process. - Reviews the dyeing process and dye house automation, and the factors that affect dyeing quality and common difficulties in the process. - Explains the principles underlying the dyeing process and provides a thorough understanding of the mathematical models that can be used to approximate it. - Discusses techniques for monitoring dyebaths and controlling the dyeing process.

This is a comprehensive book that imparts technological skills about the colouration of textiles. It discusses academic as well as shop-floor aspects of colouration. It also covers eco-friendly enzymatic processing and differential coloured effects.

Metal- Free Synthetic Organic Dyes is a comprehensive guide to the synthetic, organic dyes that are classified by their chemical structure. As synthetic dyes are playing an increasingly important role in modern life, with applications in both industry and scientific research, this book provides insights on the many research attempts that have been made to explore new photosensitizers in the development of dye sensitized solar cells (DSCs). These novel photosensitizers have incorporated, within their structure, different organic groups, such as coumarins, cyanines, hemicyanines, indolines, triphenylamines, bis(dimethylfluorenyl) aminophenyls, phenothiazines, tetrahydroquinolines, carbazoles, polyenes, fluorenes, and many others. This comprehensive resource contains color figures and schemes for each dye discussed, and is an invaluable resource for organic, inorganic and analytical chemists working in academia and industry. - Features a discussion of the synthesis of the new, high-value synthetic dyes and pigments and their applications and performance - Includes coverage of new photosensitizers and their role in the development of dye sensitized solar cells (DSCs) - Covers synthesis of the functional dyes that are ideal for applications in the dye and pigment industry, textiles, color science, solar energy materials and solar cells, biomedical sensors, advanced materials, structure and synthesis of materials, and more

Dyeing is one of the most effective and popular methods used for colouring textiles and other materials. Dyes are employed in a variety of industries, from cosmetic production to the medical sector. The two volumes of the Handbook of textile and industrial dyeing provide a detailed review of the latest techniques and equipment used in the dyeing industry, as well as examining dyes and their application in a number of different industrial sectors.Volume 1 deals with the principles of dyeing and techniques used in the dyeing process, and looks at the different types of dyes currently available. Part one begins with a general introduction to dyeing, which is followed by chapters that examine various aspects of the dyeing process, from the pre-treatment of textiles to the machinery employed. Chapters in part two then review the main types of dyes used today, including disperse dyes, acid dyes, fluorescent dyes, and many others for a diverse range of applications.With its distinguished editor and contributions from some of the world's leading authorities, the Handbook of textile and industrial dyeing is an essential reference for designers, colour technologists and product developers working in a variety of sectors, and will also be suitable for academic use. - Examines dyeing and its application in a number of different industrial sectors - Deals with the principles of dyeing and techniques used in the dyeing process, as well as types of dyes currently available - Chapters review various dye types right through to modelling and predicting dye properties and the chemistry of dyeing