Electronic Properties of Fullerenes and other Novel Materials gives an overview of the state-of-the-art research. It presents most recent results on preparation, experimental analysis by electron spectroscopy, infrared and Raman spectroscopy, luminescence, and nonlinear optical, as well as possible technological applications. Emphasis is also placed on the superconducting properties of Fullerenes. The introductory and advanced contributions provide a good survey of the current status of this rapidly developing field.

This compendium of accounts reveals the unique perspectives of many scientists who made major contributions to the Nobel Prize-winning discovery of C60 buckminsterfullerene but who have not previously published personal accounts. The introduction attempts to provide a rational framework for understanding how this discovery came about and how firmly

Until recently, the element carbon was believed to exhibit only two main allotropic forms, diamond and graphite. Research in the US and Europe has now confirmed the existence of a third previously unknown form - buckminsterfullerene ( C 60 ) and its relatives, the fullerenes ( C 24 , C 28 , C 32 , C 70 etc ). The story of fullerene chemistry, physics and materials science began in 1985, almost twenty years after the existence of a spherical carbon cluster was first considered. In September 1985 a joint Sussex/Rice Universities team including Kroto, Heath, O'Brien, Curl and Smalley used a powerful mass spectrometric technique to identify the C + 60 species, and proposed a spherical structure and the name buckminsterfullerene. It was not, however, until Krauml;tschmer and Huffman reported the isolation of crystals of C 60 in 1990 that the closed cage structure of C 60 could be confirmed. The Fullerenes documents the work leading up to 1990 and more recent developments in the field of fullerene research and will serve as an indispensible reference tool for all workers in this area.

This book provides detailed knowledge about fullerene nanowhiskers and the related low-dimensional fullerene nanomaterials. It introduces tubular nanofibers made of fullerenes, fullerene nanotubes, and single crystalline thin film made of C60, called fullerene nanosheet.Since the discovery of C60 in 1985, various fullerene molecules, including high

The Most Beautiful Molecule "The molecule, buckminsterfullerene, is beautiful physically and intellectually. Its qualities, and even some of its properties, can be appreciated instantly and intuitively by nonscientists. Its uniqueness is bound to lead to novel applications-superconductivity is the leading contender at the moment." "The commercial potential of buckminsterfullerene has heightened the excitement and controversy in recent years, while the exact nature of the discovery process in 1985 has been the subject of a heated feud between the British and American scientists involved."-Hugh Aldersey-Williams Ten years ago, the discovery of buckminsterfullerene, a previously unknown form of carbon, stunned the scientific community, as much for the discovery itself as for the manner in which it came about. In the words of author Hugh Aldersey-Williams, it was an example of "classic bootleg science". The work was done on the back of other, funded projects, and when time would allow. Yet its commercial implications are probably immense. Now, with objectivity and insight, The Most Beautiful Molecule recounts the events leading up to this momentous discovery and chronicles the ongoing, often frenzied aftermath. Hugh Aldersey-Williams leads us on a thrilling expedition to the very forefront of modern chemistry research. Houston, Texas, 1985. Two industrious chemists discover a previously unknown form of carbon and christen it buckminsterfullerene, for its striking resemblance to American architect Richard Buckminster Fuller's geodesic domes. This unusual molecule-also known as the buckyball-is composed of 60 carbon atoms arranged in a hollow sphere, with hexagonal and pentagonal configurations similar to those found on a soccer ball. Its near-perfect symmetry is just one reason why scientists have since dubbed it "the most beautiful molecule." The discovery of buckminsterfullerene-by American physicist and chemist Richard Smalley and British physical chemist Harry Kroto-rocked the scientific community. After all, generations believed graphite and diamond to be the only pure forms of carbon. How had this third form gone undetected? In fact, the actual discovery was merely the beginning of an intense-and ongoing-quest to master this newest form of the most basic of elements. Confirmation would take five years and launch an unprecedented flood of investigation and investment. The unique physical structure of buckminsterfullerene-a "cage" into which atoms of other materials may be inserted-had huge commercial potential and inspired scientists, industrial laboratories, and corporations alike. Backed by such giants as AT&T, DuPont, Exxon, and IBM, a highly competitive search for practical applications began-and continues. Possibilities range from the creation of a revolutionary rocket fuel to nanotechnology-the construction of microscopic "molecular machines"-to developments in the fight against AIDS. Here, then, is a fascinating, multilayered look at one of the most important scientific findings of our time. The Most Beautiful Molecule is a brain-teasing detective story, a marvelously detailed, inside look at the workings of the scientific community, and an exciting contemplation of what lies ahead. From the forefront of research in modern chemistry, author Hugh Aldersey-Williams offers, in his own words, "a celebration of the intimate world of physical science and its practitioners."

The creation of the hollow carbon buckminsterfullerene molecule as well as methods to produce and purify bulk quantities of it has triggered an explosive growth of research in the field. Superconducting and magnetic fullerides, atoms trapped inside the fullerene cage, chemically bonded fullerene complexes, and nanometer-scale helical carbon tubes are some of the leading areas that have generated much excitement.This book is intended as a guide to the literature for the scientist who is just entering fullerene research, and will be one more valuable volume to the collection for the established worker. It contains reprints of some sixty most important research papers, with focus especially on those papers that have guided further work in the field. There is also a short review of the field, with references to many other publications.

Krätschmer and Huffman's revolutionary discovery of a new solid phase of carbon, solid C60, in 1990 opened the way to an entire new class of materials with physical properties so diverse that their richness has not yet been fully exploited. Moreover, as a by-product of fullerene research, carbon nanotubes were later identified, from which novel nanostructures originated that are currently fascinating materials scientists worldwide. Rivers of words have been written on both fullerenes and nanotubes, in the form of journal articles, conference proceedings and books. The present book offers, in a concise and self-contained manner, the basics of the science of these materials as well as detailed information on those aspects that have so far been better explored. Structural, electronic and dynamical properties are described as obtained from various measurements and state-of-the-art calculations. Their interrelation emerges as well as their possible dependence on, for example, preparation conditions or methods of investigation. By presenting and comparing data from different sources, experiment and theory, this book helps the reader to rapidly master the basic knowledge, to grasp important issues and critically discuss them. Ultimately, it aims to inspire him or her to find novel ways to approach still open questions. As such, this book is addressed to new researchers in the field as well as experts.

There are fundamental and technological limits of conventional microfabrication and microelectronics. Scaling down conventional devices and attempts to develop novel topologies and architectures will soon be ineffective or unachievable at the device and system levels to ensure desired performance. Forward-looking experts continue to search for new paradigms to carry the field beyond the age of microelectronics, and molecular electronics is one of the most promising candidates. The Nano and Molecular Electronics Handbook surveys the current state of this exciting, emerging field and looks toward future developments and opportunities. Molecular and Nano Electronics Explained Explore the fundamentals of device physics, synthesis, and design of molecular processing platforms and molecular integrated circuits within three-dimensional topologies, organizations, and architectures as well as bottom-up fabrication utilizing quantum effects and unique phenomena. Technology in Progress Stay current with the latest results and practical solutions realized for nanoscale and molecular electronics as well as biomolecular electronics and memories. Learn design concepts, device-level modeling, simulation methods, and fabrication technologies used for today's applications and beyond. Reports from the Front Lines of Research Expert innovators discuss the results of cutting-edge research and provide informed and insightful commentary on where this new paradigm will lead. The Nano and Molecular Electronics Handbook ranks among the most complete and authoritative guides to the past, present, and future of this revolutionary area of theory and technology.

The book is a follow-up to the computerized fullerene bibliography related to the 1985-1993 period. It is a well-indexed overview of the journal literature on a topic for which the 1996 Nobel Prize in Chemistry was awarded. It is an indispensable tool for any specialist interested in the literature of one of the most researched interdisciplinary topics in the sciences.