"Presents the most comprehensive coverage available of the detection, isolation, identification, and estimation of all anionic surfactants in a wide variety of samples in trace and macro quantities. Features new chapters on volumetric and trace analysis, molecular and mass spectroscopy, and chromatographic processes."

Surfactants are used throughout industry as components in a hugerange of formulated products or as effect chemicals in theproduction or processing of other materials. A detailedunderstanding of the basis of their activity is required by allthose who use surfactants, yet the new graduate or postgraduatechemist or chemical engineer will generally have little or noexperience of how and why surfactants work. Chemistry & Technology of Surfactants is aimed at newgraduate or postgraduate level chemists and chemical engineers atthe beginning their industrial careers and those in later life whobecome involved with surfactants for the first time. The book is astraightforward and practical survey of the chemistry ofsurfactants and their uses, providing a basic introduction tosurfactant theory, information on the various types of surfactantand some application details. This will allow readers to build ontotheir scientific education the concepts and principles on which thesuccessful use of surfactants, across a wide range of industries,is based.

This work presents a comprehensive survey of important anionic surfactants. It delineates current manufacturing technologies, methods of analysis, practical applications, environmental behaviour and the physicochemical and toxicological properties of surfactants and their related by-products. The uses of anionic surfactants in the cleaning, cosmetic, textile, leather, food, petroleum, metalworking and paper industries, are encompassed.

The number of physico-chemical investigations of surfactants in solution, whether aqueous or nonaqueous, has dramatically increased in recent years. However, literature reports on surfactants in solutions are scattered over a plethora of scientific journals and books which differ widely in scope and readership. Such data are often difficult to retrieve because there have been no systematic compilations, with the exception of those for CMCs and for micelle aggregation numbers. The present compilation meets that need by covering, as completely as possible, the physico-chemical properties of selected series of homologous surfactants. These surfactants are in most cases isomerically pure, are well-known, and have been used in numerous academic and industrial studies. The properties include aggregation number, cloud point, CMC, 13C-NMR, correlation length, counterion binding, density, enthalpy of micelle formation, entropy of micelle formation, Gibbs' free energy of micelle formation, head group area, 1H-NMR, hydration number, Krafft temperature, melting point, micelle radius, microscopic viscosity, miscibility curve, partial molar volume, phase inversion temperature, refractive index, self-diffusion coefficient, surface tension, and upper critical temperature. The book also contains two- and three-component phase diagrams of many nonionic surfactants. The solvent is water in most cases; however, some data refer to properties in D2O, electrolyte solutions, and nonaqueous solvents. The variables are temperature and concentration. Where possible, the method of measurement is given. Data on the purity of the compounds and the accuracy of the measurement methods are not included, as these can easily be found in the original sources, which mostly date from the period 1970-1991 and are given at the end of each chapter. The Index section contains a compound index, a property index, a symbol index and a cross index which facilitate easy access to the data. This valuable collection of data will be of great use to anyone involved in Colloid and Surface Science, academics as well as industrial workers, and will stimulate further work.

In the tradition of the popular first edition, Analysis of Surfactants, Second Edition offers a comprehensive and practical account of analysis methods for determining and understanding commercially important surfactants-individually and in compounds. Combining a complete review of the literature with a variety of evaluation procedures and the specifications for commercial products, this useful reference explores the key stages and latest developments for surfactant applications. This edition has been thoroughly expanded and features new sections on capillary electrophoresis, ether carboxylates, and ester quats. It is also more globally accessible with foreign language citations and SI units. Containing over 2400 references, drawings, tables, and equations, Analysis of Surfactants, Second Edition is an recommended reference for physical, surface, colloid, and oil chemists; analytical, research, and quality assurance chemists working in the soap and detergent, pharmaceuticals, and cosmetic industries; regulatory and food scientists; and upper-level undergraduate and graduate students in these disciplines.

This comprehensive reference collects fundamental theories and recent research from a wide range of fields including biology, biochemistry, physics, applied mathematics, and computer, materials, surface, and colloid science-providing key references, tools, and analytical techniques for practical applications in industrial, agricultural, and forensic processes, as well as in the production of natural and synthetic compounds such as foods, minerals, paints, proteins, pharmaceuticals, polymers, and soaps.

The awareness and development of 'biodegradable' surfactants pre-dates current pressures by the environmental movement by nearly three decades, wherein a responsible industry mutually agreed to replace 'hard', non-biodegradable com ponents of household detergents by 'soft', biodegradable alternatives, without course to legislation. The only requirement at that time was for surfactants used in detergents to exhibit a 'primary biodegradability' in excess of 80%; this referring to the disap pearance or removal from solution of the intact surface active material as de tected by specified analytical techniques. This proved useful, as observed environmental impacts of surfactants, e.g. visible foam on rivers, are associated with the intact molecule. Test methods for 'primary biodegradability' were eventually enshrined in EU legislation for nonionic surfactants (Directive 821242/EEC, amended 73/404IEEC) and for anionic surfactants (Directive 8212431EEC, amended 73/405IEEC). No approved test methods and resultant legislation have been developed for cationic and amphoteric surfactants to date. The environmental classification of chemical substances, which of course includes surfactants, and associated risk assessment utilises a second criterion 'ready biodegradability'. This may be assessed by a number of methods which monitor oxygen uptake (BOD), carbon dioxide production or removal of dis solved organic carbon (DOC). Some surfactants which comply with the above Detergents Directive are borderline when it comes to 'ready biodegradability'.

""Second Edition provides a thorough, up-to-date treatment of the fundamental behavior of surface active agents in solutions, their interaction with biological structures from proteins and membranes to the stratum corneum and epidermis, and their performance in formulations such as shampoos, dentifrice, aerosols, and skin cleansers.