Algebraic Theory of Molecules presents a fresh look at the mathematics of wave functions that provide the theoretical underpinnings of molecular spectroscopy. Written by renowned authorities in the field, the book demonstrates the advantages of algebraic theory over the more conventional geometric approach to developing the formal quantum mechanics inherent in molecular spectroscopy. Many examples are provided that compare the algebraic and geometric methods, illustrating the relationship between the algebraic approach and current experiments. The authors develop their presentation from a basic level so as to enable newcomers to enter the field while providing enough details and concrete examples to serve as a reference for the expert. Chemical physicists, physical chemists, and spectroscopists will want to read this exciting new approach to molecular spectroscopy.

This text on the use of electron correlation effects in the description of the electronic structure of atoms, molecules, and crystals is intended for graduate students in physical chemistry and physics. Modern theories of electronic structure and methods of incorporating electron correlation contributions are developed using a diagrammatic and algebraic formulation, and the methods developed in the text are illustrated with examples from molecular and solid state quantum mechanics. A brief Introduction is followed by chapters on operator algebra, the independent-particle model, occupation-number formalism, and diagrams. Additional topics include the configuration-interaction method, the many-body perturbation theory, and the coupled-cluster method.

Angular Momentum Theory for Diatomic Molecules focuses on the application of angular momentum theory in describing the complex dynamical processes in molecules. The manuscript first offers information on tensor algebra and rotation group. Discussions focus on commutation relations, spherical and double tensors, rotations, coupling, reduced matrix elements, quaternions, combination theorem for Gegenbauer polynomials, and combination theorems for spherical harmonics. The book then takes a look at R(4) in physical systems and hydrogen molecular ion, including rigid rotator, reversed angular momentum, reduced matrix elements, spheroidal coordinates, and hydrogen atom in spheroidal coordinates. The publication examines expansions and free diatomic molecules. Topics include angular momentum, molecular frame, primitive energy spectrum, rotating oscillator and hydrogen atom, expressions for electric potentials, delta functions, and Neumann expansion. The manuscript also considers external fields and perturbations. The text is a dependable reference for readers interested in the application of angular momentum theory in identifying the dynamical processes going on in molecules.

This book presents the up-to-date status of quantum theory and the outlook for its development in the 21st century. The covered topics include basic problems of quantum physics, with emphasis on the foundations of quantum theory, quantum computing and control, quantum optics, coherent states and Wigner functions, as well as on methods of quantum physics based on Lie groups and algebras, quantum groups and noncommutative geometry.

As a record of an international meeting devoted to the physical and mathematical aspects of group theory, GROUP 24: Physical and Mathematical Aspects of Symmetries provides an important selection of informative articles describing recent advances in the field. The applications of group theory presented in this book deal not only with the traditional fields of physics, but also include such disciplines as chemistry and biology. Plenary session contributions are represented by 18 longer articles, followed by nearly 200 shorter articles. The book also presents coherent states, wavelets, and applications and quantum group theory and integrable systems in two separate sections.

Whenever systems are governed by continuous chains of causes and effects, their behavior exhibits the consequences of dynamical symmetries, many of them far from obvious. Dynamical Symmetry introduces the reader to Sophus Lie's discoveries of the connections between differential equations and continuous groups that underlie this observation. It develops and applies the mathematical relations between dynamics and geometry that result. Systematic methods for uncovering dynamical symmetries are described, and put to use. Much material in the book is new and some has only recently appeared in research journals. Though Lie groups play a key role in elementary particle physics, their connection with differential equations is more often exploited in applied mathematics and engineering. Dynamical Symmetry bridges this gap in a novel manner designed to help readers establish new connections in their own areas of interest. Emphasis is placed on applications to physics and chemistry. Applications to many of the other sciences illustrate both general principles and the ubiquitousness of dynamical symmetries.

This book, designed for advanced graduate students and post-graduate researchers, introduces Lie algebras and some of their applications to the spectroscopy of molecules, atoms, nuclei and hadrons. The book contains many examples that help to elucidate the abstract algebraic definitions. It provides a summary of many formulas of practical interest, such as the eigenvalues of Casimir operators and the dimensions of the representations of all classical Lie algebras.

The Highly Specialized Seminar on ?Symmetries in Nuclear Structure?, held in Erice, Italy, in March 2003, celebrated the career and the remarkable achievements of Francesco Iachello, on the occasion of his 60th birthday. Since the development of the interacting boson model in the early 1970s, the ideas of Iachello have provided a variety of frameworks for understanding collective behaviour in nuclear structure, founded on the concepts of dynamical symmetries and spectrum-generating algebras. The original ideas, which were developed for the description of atomic nuclei, have now been successfully extended to cover spectroscopic behaviour in other fields, such as molecular or hadronic spectra. More recently, the suggestion by Iachello of critical point symmetries to treat nuclei in shape/phase transitional regions has opened an exciting new front for both theoreticians and experimentalists.The talks presented at the meeting covered many of the most active forefront areas of nuclear structure as well as other fields where ideas of symmetries are being explored. Topics in nuclear structure included extensive discussions on dynamical symmetries, critical point symmetries, phase transitions, statistical properties of nuclei, supersymmetry, mixed symmetry states, shears bands, pairing and clustering in nuclei, shape coexistence, exotic nuclei, dipole modes, and astrophysics, among others. In addition, important sessions focused on talks by European laboratory directors (or their representatives) outlining prospects for nuclear structure, and the application of symmetry ideas to molecular phenomena. Finally, a special lecture by Nobel laureate Alex Mueller, on s and d wave symmetry in superconductors, presented a unique insight into an allied field.The proceedings have been selected for coverage in: ? Index to Scientific & Technical Proceedings? (ISTP? / ISI Proceedings)? Index to Scientific & Technical Proceedings (ISTP CDROM version / ISI Proceedings)? CC Proceedings ? Engineering & Physical Sciences

Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.

Mathematics for Physical Chemistry, Third Edition, is the ideal text for students and physical chemists who want to sharpen their mathematics skills. It can help prepare the reader for an undergraduate course, serve as a supplementary text for use during a course, or serve as a reference for graduate students and practicing chemists. The text concentrates on applications instead of theory, and, although the emphasis is on physical chemistry, it can also be useful in general chemistry courses. The Third Edition includes new exercises in each chapter that provide practice in a technique immediately after discussion or example and encourage self-study. The first ten chapters are constructed around a sequence of mathematical topics, with a gradual progression into more advanced material. The final chapter discusses mathematical topics needed in the analysis of experimental data. - Numerous examples and problems interspersed throughout the presentations - Each extensive chapter contains a preview, objectives, and summary - Includes topics not found in similar books, such as a review of general algebra and an introduction to group theory - Provides chemistry specific instruction without the distraction of abstract concepts or theoretical issues in pure mathematics