Although the basic theories of thermodynamics are adequately covered by a number of existing texts, there is little literature that addresses more advanced topics. In this comprehensive work the author redresses this balance, drawing on his twenty-five years of experience of teaching thermodynamics at undergraduate and postgraduate level, to produce a definitive text to cover thoroughly, advanced syllabuses. The book introduces the basic concepts which apply over the whole range of new technologies, considering: a new approach to cycles, enabling their irreversibility to be taken into account; a detailed study of combustion to show how the chemical energy in a fuel is converted into thermal energy and emissions; an analysis of fuel cells to give an understanding of the direct conversion of chemical energy to electrical power; a detailed study of property relationships to enable more sophisticated analyses to be made of both high and low temperature plant and irreversible thermodynamics, whose principles might hold a key to new ways of efficiently covering energy to power (e.g. solar energy, fuel cells). Worked examples are included in most of the chapters, followed by exercises with solutions. By developing thermodynamics from an explicitly equilibrium perspective, showing how all systems attempt to reach a state of equilibrium, and the effects of these systems when they cannot, the result is an unparalleled insight into the more advanced considerations when converting any form of energy into power, that will prove invaluable to students and professional engineers of all disciplines.

An advanced, practical approach to the first and second laws of thermodynamics Advanced Engineering Thermodynamics bridges the gap between engineering applications and the first and second laws of thermodynamics. Going beyond the basic coverage offered by most textbooks, this authoritative treatment delves into the advanced topics of energy and work as they relate to various engineering fields. This practical approach describes real-world applications of thermodynamics concepts, including solar energy, refrigeration, air conditioning, thermofluid design, chemical design, constructal design, and more. This new fourth edition has been updated and expanded to include current developments in energy storage, distributed energy systems, entropy minimization, and industrial applications, linking new technologies in sustainability to fundamental thermodynamics concepts. Worked problems have been added to help students follow the thought processes behind various applications, and additional homework problems give them the opportunity to gauge their knowledge. The growing demand for sustainability and energy efficiency has shined a spotlight on the real-world applications of thermodynamics. This book helps future engineers make the fundamental connections, and develop a clear understanding of this complex subject. Delve deeper into the engineering applications of thermodynamics Work problems directly applicable to engineering fields Integrate thermodynamics concepts into sustainability design and policy Understand the thermodynamics of emerging energy technologies Condensed introductory chapters allow students to quickly review the fundamentals before diving right into practical applications. Designed expressly for engineering students, this book offers a clear, targeted treatment of thermodynamics topics with detailed discussion and authoritative guidance toward even the most complex concepts. Advanced Engineering Thermodynamics is the definitive modern treatment of energy and work for today's newest engineers.

Innovative, wide-ranging treatment, suitable for advanced undergraduates and graduate students, covers negative temperatures and heat capacities, general and special relativistic effects, black hole thermodynamics, gravitational collapse, and more. Problems with worked solutions. 1978 edition.

If a Writer would know how to behave himself with relation to Posterity; let him consider in old Books, what he finds, that he is glad to know; and what Omissions he most laments. Jonathan Swift This book emerges from a long story of teaching. I taught chemical engineering thermodynamics for about ten years at the University of Naples in the 1960s, and I still remember the awkwardness that I felt about any textbook I chose to consider-all of them seemed to be vague at best, and the standard of logical rigor seemed immensely inferior to what I could find in books on such other of the students in my first class subjects as calculus and fluid mechanics. One (who is now Prof. F. Gioia of the University of Naples) once asked me a question which I have used here as Example 4. 2-more than 20 years have gone by, and I am still waiting for a more intelligent question from one of my students. At the time, that question compelled me to answer in a way I didn't like, namely "I'll think about it, and I hope I'll have the answer by the next time we meet. " I didn't have it that soon, though I did manage to have it before the end of the course.

Designed for the course in thermodynamics or for use as a reference for practicing engineers, this book includes the theoretical underpinnings and derivations necessary for advanced study. The book focuses on the mechanical and power engineering applications of thermodynamics. Mathematics is utilized as required, serving as a tool to formulate the concepts, solve problems and applications. Furthermore, numerous examples are provided to demonstrate the applications of thermodynamics for engineering problems and to enhance the use of concepts. It also includes statistical thermodynamic examples when relevant and pertinent. These examples are shown either conceptually or numerically. Features: +Numerous examples are provided to demonstrate the applications of thermodynamics for engineering problems +Includes a comprehensive and generalist view of thermodynamics, along with historical developments in the field +Presents mathematical tools such as the Legendre transformation, the Euler chain rule, the Jacobian methodology and applications for thermodynamic derivatives.

This book is an excellent companion to Chemical Thermodynamics: Principles and Applications. Together they make a complete reference set for the practicing scientist. This volume extends the range of topics and applications to ones that are not usually covered in a beginning thermodynamics text. In a sense, the book covers a "middle ground" between the basic principles developed in a beginning thermodynamics textbook, and the very specialized applications that are a part of an ongoing research project. As such, it could prove invaluable to the practicing scientist who needs to apply thermodynamic relationships to aid in the understanding of the chemical process under consideration. The writing style in this volume remains informal, but more technical than in Principles and Applications. It starts with Chapter 11, whichsummarizes the thermodynamic relationships developed in this earlier volume. For those who want or need more detail, references are given tothe sections in Principles and Applications where one could go to learn more about the development, limitations, and conditions where these equations apply. This is the only place where Advanced Applications ties back to the previous volume. Chapter 11 can serve as a review of the fundamental thermodynamic equations that are necessary for the more sophisticated applications described in the remainder of this book. This may be all that is necessary for the practicing scientist who has been away from the field for some time and needs some review. The remainder of this book applies thermodynamics to the description of a variety of problems. The topics covered are those that are probably of the most fundamental and broadest interest. Throughout the book, examples of "real" systems are used as much as possible. This is in contrast to many books where "generic" examples are used almost exclusively. A complete set of references to all sources of data and to supplementary reading sources is included. Problems are given at the end of each chapter. This makes the book ideally suited for use as a textbook in an advanced topics course in chemical thermodynamics. - An excellent review of thermodynamic principles and mathematical relationships along with references to the relevant sections in Principles and Applications where these equations are developed - Applications of thermodynamics in a wide variety of chemical processes, including phase equilibria, chemical equilibrium, properties of mixtures, and surface chemistry - Case-study approach to demonstrate the application of thermodynamics to biochemical, geochemical, and industrial processes - Applications at the "cutting edge" of thermodynamics - Examples and problems to assist in learning - Includes a complete set of references to all literature sources

Advanced Thermodynamics Engineering, Second Edition is designed for readers who need to understand and apply the engineering physics of thermodynamic concepts. It employs a self-teaching format that reinforces presentation of critical concepts, mathematical relationships, and equations with concrete physical examples and explanations of applications—to help readers apply principles to their own real-world problems. Less Mathematical/Theoretical Derivations—More Focus on Practical Application Because both students and professionals must grasp theory almost immediately in this ever-changing electronic era, this book—now completely in decimal outline format—uses a phenomenological approach to problems, making advanced concepts easier to understand. After a decade teaching advanced thermodynamics, the authors infuse their own style and tailor content based on their observations as professional engineers, as well as feedback from their students. Condensing more esoteric material to focus on practical uses for this continuously evolving area of science, this book is filled with revised problems and extensive tables on thermodynamic properties and other useful information. The authors include an abundance of examples, figures, and illustrations to clarify presented ideas, and additional material and software tools are available for download. The result is a powerful, practical instructional tool that gives readers a strong conceptual foundation on which to build a solid, functional understanding of thermodynamics engineering.

Furthermore, a chapter on the microscopic implications of the entropy function and the second law is also included.

Using an applications perspective Thermodynamic Models for Industrial Applications provides a unified framework for the development of various thermodynamic models, ranging from the classical models to some of the most advanced ones. Among these are the Cubic Plus Association Equation of State (CPA EoS) and the Perturbed Chain Statistical Association Fluid Theory (PC-SAFT). These two advanced models are already in widespread use in industry and academia, especially within the oil and gas, chemical and polymer industries. Presenting both classical models such as the Cubic Equations of State and more advanced models such as the CPA, this book provides the critical starting point for choosing the most appropriate calculation method for accurate process simulations. Written by two of the developers of these models, Thermodynamic Models for Industrial Applications emphasizes model selection and model development and includes a useful “which model for which application” guide. It also covers industrial requirements as well as discusses the challenges of thermodynamics in the 21st Century.