Corrosion due to water is one of the most significant and complex causes of damage to metallic products. Written from the viewpoint of physical chemistry, this authoritative and established text deals with the aqueous corrosion of metals. Available for the first time in English, Corrosion of Metal addressing engineers, metallurgists, physicists and chemists. This self-contained, valuable reference comprehensively organizes and makes readily accessible the accumulated wealth of fundamental and applied knowledge. The concentration is on the underlying essentials of corrosion and failure, and the material is consistently presented in relation to practical applications to corrosion protection. The first chapters introducing the physicochemical principles are ideal for students. The following chapters provide an overview of the state of research for those familiar with the fundamentals. An exhaustive bibliography and appendices conclude the volume.

Understanding corrosion is essential for selecting and maintaining equipment and structural components that will withstand environmental and process conditions effectively. Fundamentals of Metallic Corrosion: Atmospheric and Media Corrosion of Metals focuses on the mechanisms of corrosion as well as the action of various corrodents on metals and th

The book is concerned with understanding the fundamental mechanisms of high temperature alloy oxidation. It uses this understanding to develop methods of predicting oxidation rates and the way they change with temperature, gas chemistry and alloy composition. The focus is on designing (or selecting) alloy compositions which provide optimal resistance to attack by corrosive gases. . Emphasises quantitative calculations for predicting reaction rates and the effects of temperature, oxidant activities and alloy compositions. . Uses phase diagrams and diffusion paths to analyse and interpret scale structures and internal precipitation distributions . Provides a detailed examination of corrosion in industrial gases (water vapour effects, carburisation and metal dusting, sulphidation) . Text is well supported by numerous micrographs, phase diagrams and tabulations of relevant thermodynamic and kinetic data . Combines physical chemistry and materials science methodologies.

Introduction and Scope-During the last few decades, an enormous effort has been made to understand corrosion phenomena and their mechanisms, and to elucidate the causes that dramatically influence the service lifetime of metal materials. The performance of metal materials in aggressive environments is critical for a sustainable society. The failure of the material in service impacts the economy, the environment, health, and society. In this regard, corrosion-based economic losses due to maintenance, repair, and the replacement of existing structures and infrastructure account for up to 4% of gross domestic product (GDP) in well developed countries. One of the biggest issues in corrosion engineering is estimating service lifetime. Corrosion prediction has become very difficult, as there is no direct correlation with service lifetime and experimental lab results, usually as a result of discrepancies between accelerated testing and real corrosion processes. It is of major interest to forecast the impact of corrosion-based losses on society and the global economy, since existing structures and infrastructure are becoming old, and crucial decisions now need to be made to replace them. On the other hand, environmental protocols seek to reduce greenhouse effects. Therefore, low emission policies, in force, establish regulations for the next generation of materials and technologies. Advanced technologies and emergent materials will enable us to get through the next century. Great advances are currently in progress for the development of corrosion-resistant metal materials for different sectors, such as energy, transport, construction, and health. This Special Issue on the corrosion and protection of metals is focused on current trends in corrosion science, engineering, and technology, ranging from fundamental to applied research, thus covering subjects related to corrosion mechanisms and modelling, protection and inhibition processes, and mitigation strategies.

Corrosion may be defined as an unintentional attack on a material through reaction with a surrounding medium. The term can refer to a process or to the damage caused by such a process. According to this general definition, materials other than metals, such as ceramics, plastics or concrete, may also be subject to corrosion (or corrode). When no particular reference is made to the material, however, it is normally understood that a metal is being attacked. It is entirely in this limited sense that the term is used in this book. There are good reasons for treating the corrosion of metals separately, apart from deterioration or decay of other materials. Since metals have a high electric conductivity, their corrosion is usually of an electrochemical nature. The chemical deterioration of electrically non-conducting ma terials, such as plastics and ceramics, is governed by other physico-chemical principles. It is necessary to devote more attention to metallic corrosion nowadays than earlier, due to 1. An increased use of metals within all fields of technology. 2. The use for special applications, e.g. within the atomic energy field, of rare and expensive metals, whose preservation requires particular precautions. 3. A more corrosive environment due to the increasing pollution of air and water. 4. The use of metallic constructions of more slender dimensions which do not tolerate corrosive attacks to the same extent as did the heavy constructions used in the old days.

Textbook; grad.

It is estimated that about 40% of the annual production of metals is used to repair or replace materials damaged by corrosion. Corrosion causes waste of the natural material and energy resources, it creates serious materials problems for many technologies and adversely affects almost every area of engineering. The use of metals in various aggressive environments has resulted in an extremely wide diversity of corrosion problems. This book presents a collection of concise reviews written by experts in the field on selected topics of metallic corrosion and on some aspects of interaction of hydrogen with metals. A comprehensive range of problems is examined including localized corrosion, high temperature corrosion in liquid metals and molten salts, transport control in corrosion processes, entry of hydrogen into metals, hydrogen embrittlement, and hydrogen reactions with metals. The variety of topics covered in the book will provide corrosion scientists, engineers, university lecturers and students alike with an interdisciplinary approach to solving problems of materials degradation and surface processes in metal corrosion.

Covering the essential aspects of the corrosion behavior of metals in aqueous environments, this book is designed with the flexibility needed for use in courses for upper-level undergraduate and graduate students, for concentrated courses in industry, for individual study, and as a reference book.

The Corrosion Resistant Metals Committee and the Nuclear Metallurgy Committee of the Institute of Metals Division of The Metallurgical Society of AlME sponsored a 2-1/2 day symposium on "Corrosion by Liquid Metals". The symposium was held in Philadelphia, October 13-15, 1969, during the 1969 Fall Meeting of the Metallurgical Society and the Materials Engineering Con gress of the American Society for Metals. Cosponsors included the American Society for Metals and the American Nuclear Society. The purpose of the symposium was to bring together the several aspects of the subject of corrosion by liquid metals, so that perspective could be provided on the entire subject, to help in dividuals dealing with liquid metal corrosion problems acquire a sound basis of understanding, and to provide an opportunity for discussion between those doing research in this field. An exposition of the subject is timely, in view of the in creasing development of liquid metal heat and power sources for special purposes, including heat-pipe systems, NASA's SNAP power systems, and the AEC's liquid metal fast breeder reactor system. This book contains the proceedings of the symposium divided into four separate topics: I. Corrosion of Steels by Sodium, II. Alkali-Refractory Metal Interactions, III. Corrosion by Non-Alkali Metals, and IV. Analysis of Solid-Liquid Metal Inter actions (two sessions).